The Nikon D700 can be used as a master/commander flash unit. The D700 is however limited to
2 groups of flashes, compared to 3 groups on the SU-800

Press menu and navigate to the custom setting menu, the one with the pen icon on it, then choose sub-menu e. To confirm selection You can press enter, right on the multi selector, or the center of the multiselector.

Navigate to custom setting e3. Confirm the selection.

On this screen you have four choices, TTL, M, RPT and Commander mode. Pick commander mode and confirm selection.

In this menu, you set-up the different modes you want for you`r wireless flash needs. Press enter when you are done, and you are ready to use the D700 as a master/commander flash unit.
If you followed the steps above you should now see a C next to the flash icon in custom setting #e3. This tells you that the camera is now in commander mode.
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